QUALITY PARAMETERS OF WATER
Water impurities are classified as physical,
chemical and biological impurities
PHYSICAL WATER QUALITY PARAMETER
Suspended solids,
Turbidity,
Colour,
Taste and odour,
Temperature
SUSPENDED SOLIDS
Source:
These are called as physical parameters
whereas dissolved solids are considered as
chemical parameters. Suspended solids
comes from inorganic particles like silt, clay
etc., Immiscible liquids like oils and greases
and organic particles like plant fiber, algae,
etc. Inorganic solids are non-degradable
solids.
Note: Problem of Suspended Solid comes only in surface water not in ground water.
Objection:
These are objectionable because
(a) Aesthetically displeasing.
(b)It provides adsorption sites for
chemical and biological agents
(c) They may also be biologically active and
may form disease causing organisms as
well as organisms such as toxin
producing strains of algae.
Measurement
Most of the methods are gravimetric i.e.
SS are calculated by weighing them.
Total solids i.e. all solids (suspended or
dissolved) are calculated by
evaporating the sample and measuring
the residue. Heating temperature is
104°C. Suspended solid is obtained by
filtration and heading the residue on
filter at 104°C Dissolved solids (DS) = Total solids (TS)– Suspended solids(SS)
Note: Filtration in real terms does not
exactly divides the solids into
suspended and dissolved fractions
because some colloids may pass
through the filter and can get measured
along with dissolved fraction. Hence,
classification is does as filterable solids.
Hence suspended solids are
corresponding to non – filterable solids
and dissolved solids are corresponding
to filterable solids.
The organic content of both total and
dissolved solid can be determined by
firing the residue at 6000C.
Organic fraction
600CCO2 + Water +
Other gases
The Permissible limits
For suspended solid as per EPA
(Environmental Protection Agency) is 30
mg/l
TURBIDITY
Source:
Turbidity is the measure of extent to which
light is either absorbed or scattered by
suspended material in water. It is not a
direct quantitative measure of suspended
solids.
Objection:
Disinfection of turbid water is difficult
because the suspended solids may
partially shield the organisms from
disinfectant.
In natural bodies, turbidity interferes
with light penetration and hence with
the photosynthetic reactions (which
gives oxygen to the water).
Measurement
Measurement of turbidity is done using the
following:
Turbidity rod
Jackson’s turbid meter
Baylis turbid meter
Nephlometer
Turbidity rod
Rod with platinum needle is inserted
water and the depth at which platinum
needle just becomes invisible gives
turbidity in ppm.
As depth of insertion increases, reading
will decrease.
Turbidity which one milligram of finely
divided silica produces in one liter of
distilled water is taken as one unit.
The permissible limit is 5 – 10 ppm.
It is a field method.
Note:GOI manual gives turbidity in NTU
i.e. Nephelometer turbidity unit. Acc
Jackson’s Turbid meter
The level of water is increased till the
image of flame ceases to be seen.
The turbidity is measured from
graduated glass tube.
It is used when turbidity is greater than
25 ppm.
It is a laboratory method.
This method is not used for drinking
water.
Note:Turbid raw water of natural
source has turbidity greater than 25
ppm.
Baylis Turbid meter and Nephelometer
Baylis and Nephelometer turbid meters
are based on colour matching techniques.
In this case even a small turbidity of one
unit or less can be measured.
Hence these are most widely used for
domestic water supplies.
In Baylis turbiditymeter light intensity
is measured in the direction of incident
light only where as in Nephelometer
light intensity is measured as right
angles to the incident ray.
Hence NTU is based in Scattering
principle.
If Formazine, a chemical, is used as base
in place of SiO2. The turbidity is also
sometimes called FTU.
COLOUR
Source
Colour is caused by suspended and
dissolved matter in water.
After suspended matter causing colour
is removed by centrifugation, the colour
obtained is called true colour.
Humic acid gives yellowish brown
colour, Iron oxide gives reddish colour,
manganese oxide gives brown or
blackish water.
Water containing oxidized iron and
manganese impart characteristic
reddish or black colour. Heavy growth
of algae may also impart colour to the
water.
Objection
Coloured water is not suitable for dying
purpose.
Organic compounds causing colour may
exert chlorine demand and hence
reduces the effectiveness of disinfection
by chlorine.
Phenolic compound with chlorine
produces taste and odour.
Some colour causing organic
compounds with chlorine becomes
carcinogenic.
Measurement
Measurement of colour is done by colour
matching technique (tintometer).
Result is expressed in TCU or Hazen
unit (True colour unit) where 1 TCU is
equal to color produced by 1 mg per
litre of platinum in the form of
chloroplatination (It is only for
yellowish brown color)
For colour other than yellowish brown
i.e. from industrial effluent, spectro
photometric technique is used.
The colour testing is done within 72
hours of collection as otherwise
biological or physical properties may
change.
Permissble limit: Acceptable limit is 5
TCU and cause for rejection is 25 TCU.
TASTE AND ODOUR
Taste and odour are caused by dissolve
gasses like H2S (Hydrogen sulphide),
mercaptans, methan, organic matter
derived from certain dead or living
microorganism, decomposing organic
matter, industrial liquid, waters
containing phenols , cresols , ammonia ,
agricultural chemicals, high residual
chlorine and chloro-phenols.
Source
Sulphur imparts rotten egg like taste
and odour.
Algae secretes oily substances that may
result in bad taste and odour.
Objection: The taste and odour causing
compounds may be carcinogenic.
Measurement
Measurement of taste and odour
causing organics can be done using gas
or liquid chromatography. However this
method is costly and not done in
routine.
Odour is generally measured by an
instrument known as somoscope.
Intensity of taste and odour is
measured by Threshold odour
number. (TON)
It represents the dilution ratio at which
odour is hardly detectable.
TON allowed is between 1 – 3.
TON testing is done in cold water
because increase in temperature may
Change the taste and odour.
The formula for TON =
A+B/A
where A is
the volume of odours water in mL and B
is the volume of odour free water
required to procedure a mixture in
which odour is hardly detectable.
Odour can be removed by mechanical
aeration, oxidation by chemicals like
chlorine or its compounds or ozone or
permanganate and adsorption of odour
by agents such as activated carbon. Floc
or clays.
Temperature
Temperature affects the chemical and
biological reactions. An increase in 10°C
, doubles the biological activity. Hence
for water supply, the temperature
should be between 10-25°C and greater
than 25°C is objectional.
Physical water quality parameters
Reviewed by Digitech education
on
April 23, 2020
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